Advances in Membrane Separation for Biomaterial Dewatering.

Biomaterials often contain large quantities of water (50-98%), and with the current transition to a more biobased economy, drying these materials will become increasingly important. Contrary to the standard, thermodynamically inefficient chemical and thermal drying methods, dewatering by membrane separation will provide a sustainable and efficient alternative. However, biomaterials can easily foul membrane surfaces, which is detrimental to the performance of current membrane separations. Improving the antifouling properties of such membranes is a key challenge. Other recent research has been dedicated to enhancing the permeate flux and selectivity. In this review, we present a comprehensive overview of the design requirements for and recent advances in dewatering of biomaterials using membranes. These recent developments offer a viable solution to the challenges of fouling and suboptimal performances. We focus on two emerging development strategies, which are the use of electric-field-assisted dewatering and surface functionalizations, in particular with hydrogels. Our overview concludes with a critical mention of the remaining challenges and possible research directions within these subfields.

PNIPAM Brushes in Colloidal Photonic Crystals Enable Ex Situ Ethanol Vapor Sensing.

Structural colors are formed by the periodic repetition of nanostructures in a material. Upon reversibly tuning the size or optical properties of the repetitive unit inside a nanostructured material, responsive materials can be made that change color due to external stimuli. This paper presents a simple method to obtain films of ethanol vapor-responsive structural colors based on stacked poly(N-isopropylacrylamide) (PNIPAM)-grafted silica nanoparticles. Our materials show clear, reversible color transitions in the presence of near-saturated ethanol vapor. Moreover, due to the absorption of ethanol in the PNIPAM brushes, relatively long recovery times are observed (∼30 s). Materials based on bare or poly(methyl methacrylate) (PMMA) brush-grafted silica nanoparticles also change color in the presence of ethanol vapor but possess significantly shorter recovery times (∼1 s). Atomic force microscopy reveals that the delayed recovery originates from the ability of PNIPAM brushes to swell in ethanol vapor. This renders the films highly suitable for ex situ ethanol vapor sensing.